元宝草{口(左)山(右)}酮成分的研究

郭澄;郑清明;郑汉臣

中国药学杂志 ›› 2007, Vol. 42 ›› Issue (06) : 418-419.

中国药学杂志 ›› 2007, Vol. 42 ›› Issue (06) : 418-419.
论著

元宝草{口(左)山(右)}酮成分的研究

  • 郭澄;郑清明,;郑汉臣
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Study on Xanthones from Hypericum samponii Hance

  • GUO Cheng1, ZHENG Qing-ming1,2, ZHENG Han-chen2
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摘要

目的对元宝草的化学成分进行研究。方法利用硅胶、聚酰胺、Sephadex LH-20和大孔树脂柱色谱对化合物进行分离,并用光谱方法进行结构鉴定。结果分离鉴定了4个酮类成分:1-羟基-7-甲氧基酮(Ⅰ)、1,3,5-三羟基酮(Ⅱ)、1,3,6,7-四羟基酮(Ⅲ)和芒果苷(Ⅳ)。结论除化合物Ⅳ外,均为首次从该植物中分离得到。

Abstract

OBJECTIVE To study the chemical constituents of Hypericum sampsonii Hance.METHODS The compounds were isolated by silica gel,polyamide,sephadex LH-20 and macroreticular resin,and the structures were elucidated by UV,IR,MS,1H-NMR,13C-NMR and their physicochemical properties.RESULTS Four xanthone compounds were isolated from the aerial parts and identified as 1-hydroxy-7-methoxyxantone(Ⅰ),1,3,5-trihydroxyxanthone(Ⅱ),1,3,6,7-tetrahydroxy-xanthone(Ⅲ) and mangiferin(Ⅳ).CONCLUSION All these compounds are obtained from this plant for the first time except for the compound Ⅳ.

关键词

元宝草 / 化学成分 / 酮

Key words

Hypericum sampsonii Hance / chemical constituents / xanthones

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导出引用
郭澄;郑清明;郑汉臣. 元宝草{口(左)山(右)}酮成分的研究[J]. 中国药学杂志, 2007, 42(06): 418-419
GUO Cheng;ZHENG Qing-ming;ZHENG Hn-chen. Study on Xanthones from Hypericum samponii Hance [J]. Chinese Pharmaceutical Journal, 2007, 42(06): 418-419

参考文献

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