OBJECTIVE To study the chemical constituents of the bark of Fraxinus mandschurica Rupr. METHODS The compounds were isolated and purified by column chromatography with silica. Their structures were elucidated on the basis of physicochemical properties and spectral analysis. RESULTS Six compounds were identified as calceolarioside A (Ⅰ), calceolarioside B (Ⅱ), calceolarioside A-2′-α-L-rhamnopyranoside(Ⅲ), homovanillyl alcohol-4￠-glycoside(Ⅳ), ligstroside(Ⅴ), balanophonin(Ⅵ). CONCLUSION CompoundⅠ,Ⅱ, Ⅲ, Ⅵ and Ⅶ are isolated from the bark of Fraxinus mandschurica Rupr. for the first time and compound Ⅲ is a new one.
Key words
Fraxinus mandschurica Rupr. /
phenethyl alcohol glycoside /
chemical constituent /
calceolarioside A-2′-α-L-rhamnopyranoside
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References
[1] LI S D ， SUN S G. Study on chemical constituents from Fraxinus mandschurica Rupr. [J] . <> Chin Tradit Herbal Drugs ( 中草药 ) ， 1987 ， 18 （ 2 ）： 43.
[2] LIU D L, ZHANG Y, XU S X, <>et al. Phenylethanoid glycosides from <>Forsythia suspense Vahl[J]. <>J Chin Pharm Sci ( 中国药学 ), 1998, 7(2):103-105.
[3] WANG M Y, YANG L, TU Y Y. Phenylethanoid glycosides from stem of Chirita longgangensis var. hongyao [J]. <>Chin Pharm J ( 中国中药杂志 ) ， 2005 ， 30 （ 24 ）： 1921-1923.
[4] CHRISTOPHORIDOU S, DAIS P. Detection and quantification of phenolic compounds in olive oil by high resolution 1H nuclear magnetic resonance spectroscopy [J]. <>Anal Chim Acta ， 2009 ， 633(2) ： 283-292.
[5] IHSAN C, MOHANNED H, MOHAMMED F L. A secoiridoid glucoside from <>Fraxinus <>angustifolia[J]. <>Phytochemistry, 1996, 41(6) ： 1557-1562.
[6] TANYA I, BERNHARD V, IVANKA K. Secoiridoid glucodisdes from <>Fraxinus <>ornus bark[J]. <>Phytochemistry, 1998, 49(5) ： 1329-1332.
[7] GAO F ， LI X ， WU L J ， <> et al ． The studies on the NMR spectra of dihydrobenzofuran lignans [J]. <>J Chin Magn Reson ( 波谱学杂志 ) ， 1997 ， 14(5) ： 425-429 ．
[8] LI H X ， LI X ， WANG J H. Chemical constituents of Nux prinsepiae uniflorae[J]. <> J Shenyang Pharm Univ ( 沈阳药科大学学报 ) ， 2006 ， 23 （ 4 ）： 209-231.
（收稿日期： 2008-12-21 ）
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