摘要
目的研究玉簪[Hosta plantaginea(Lam.)Aschers]花的化学成分。方法采用硅胶柱色谱,Sephadex LH-20柱色谱进行系统分离。通过理化性质和波谱学方法鉴定化合物结构。结果从体积分数95%乙醇提取物中分离得到了6个化合物,分别鉴定为正二十烷酸(Ⅰ),棕榈酸-α-单甘油酯(Ⅱ),山柰酚(Ⅲ),槲皮素(Ⅳ),山柰酚-3-O-芸香糖苷(Ⅴ),山柰酚-7-O-β-D-葡萄糖苷(Ⅵ)。结论6个化合物均为首次从该植物中得到。化合物Ⅰ,Ⅱ,Ⅲ,Ⅳ,Ⅵ为首次从该属植物中得到。
Abstract
OBJECTIVE To investigate the chemical constituents of Hosta plantaginea(Lam.) Aschers.METHODS The chemical constituents were isolated by Sephadex LH-20 and silica gel column chromatography.The structures of these compounds were identified by physiochemical properties and spectral analysis.RESULTS Six compounds were isolated from the 95%ethanol extract of the flowers of Hosta plantaginea(Lam.) Aschers and elucidated as eicosan acid(Ⅰ),hexadecanoic acid 2,3-dihydroxypropyl ester(Ⅱ),kaempferol(Ⅲ),quercertin(Ⅳ),kaempferol-3-O-rutinoside(Ⅴ),kaempferol-7-O-β-D-glucoside(Ⅵ).CONCLUSION Six compounds were isolated from Hosta plantaginea(Lam.) Aschers for the first time.CompoundⅠ,Ⅱ,Ⅲ,ⅣandⅤwere isolated from the genus for the first time.
关键词
玉簪花 /
化学成分
{{custom_keyword}} /
Key words
Hosta plantaginea
{{custom_keyword}} /
解红霞;张金花;张宏桂;薛培凤.
蒙药玉簪花的化学成分研究[J]. 中国药学杂志, 2009, 44(10): 733-735
XIE Hong-xi;ZHNG Jin-hu;ZHNG Hong-gui;XUE Pei-feng.
Studies on Chemical Constituents from Hosta plantaginea(Lam.) Aschers,a Mongolia Medicine [J]. Chinese Pharmaceutical Journal, 2009, 44(10): 733-735
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] LUO B S.Identification Pharmaceutics(识药学蒙文版)[M].Hohhot: Inner Mongolia People's Press,1998,61.
[2] KEN'ICHI T, TAMETO O, HITOSHI M, et al. Studies on the steroidal components of domestic plants.XLV.Constituents of Domestic Plants.[J].Chem Pharm Bull,1964,21(7):779-783.
[3] JAROMIR B. Kaempferol glycosides from Hosta ventricosa. [J]. Phytochemitry,1990,29(11):3643-3647.
[4] YOSHIHIRO M,TOSHIHIRO K,MINPEI K, et al.Steroidal saponins from the Underground Part of Hosta longipes and Their Inhibitory Activity on Tumour Promoter-Induced Phospholipid Metabolism. [J]. Phytochemitry,1995,43(7):1190-1196.
[5] YOSHIHIRO M,MINPEI K,AIKO K, et al. Steroidal saponins from the rhizomes of Hosta sieboldii and their cytostatic activity on HL-60 cells. [J]. Phytochemitry,1998,48(8):1361-1369.
[6] WANG Y H,ZHANG Z K,YANG F M,et al. Benzylphenethylamine Alkaloids from Hosta plantaginea with Inhibitory Activity against Tobacco Mosaic Virus and Acetylcholinesterase.[J]. J Nat Prod,2007,70:1458-1461.
[7] ZHANG L,FEN Y L,DING A W. The Reserrch on the Chemical components of Schizonepeta tenuifolia Briq. [J]. J Chin Med Mater (中药材),2001,24(3):183-185.
[8] LAI X Y,ZHAO Y Y,LIANG H. Studies on Chemical Consitituents in flower of Abelmoschus manihot. [J].China J Chin Mater Med(中国中药杂志),2006,31 (19):1597-1600.
[9] AGRAWAL P K. Carbon-13 NMR of flavoids[M]. New York: Elsevier Scientific Publishing Company,1989,208-209.
[10] YIN Z Q,CHAO J F,ZHANG L H,et al. Chemical constituents from Broussonetia papyrifera (L.) vent. [J]. Nat Prod Res Dev (天然产物研究与开发),2006,18(3):420-422.
[11] LI N,LI X,YANG S L,et al. Studies on chemical constituents of the total flavonoids from Comptosorus sibiricus Rupr. [J]. J Shenyang Pharm Univ (沈阳药科大学学报),2004,21(2):105-108.
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}